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ConclusionsIt has been shown that an interdisciplinary physical-chemical approach, using X-ray absorption spectroscopy, X-ray powder diffraction, sequential extraction and hyphenated speciation techniques, allows for unmatched unravelling of the arsenic presence in a calciner residue dump. In a soil depth profile from the dump and a mixed soil sample the following arsenic concentrations were measured: 0.287% (15-20 cm), 15.41% (20-25 cm), 8.82% (25-30 cm) and 1.081% (0-30 cm, mixed soil). Based on the results from the different physical-chemical approaches, the following general conclusions from analysis of these samples may be drawn:
Acknowledgments The authors would like to thank Simon Camm from UEC for preparing the samples and the Slovene Ministery of Science, Education and Sport and the British Council for support in the framework of a bilateral Partnership for Science Project (PSP 2004/22). X-ray absorption measurements at HASYLAB, Hamburg were supported by the European Community - Research Infrastructure Action under the FP6 "Structuring the European Research Area" Programme, through the Integrated Infrastructure Initiative" Integrating Activity on Synchroton and Free Electron Laser Science (IHP-Contract HPRI-CT-1999-00040), and the bilateral project BI-DE/03-04-004 by Internationales Buero des BMBF. Provision of synchrotron radiation facilities by European Synchrotron Radiation Facility (proposal HE-1522) and HASYLAB (project II-01-44) are acknowledged. We would like to thank Gloria Subias Peruga of ESRF beamline BM29 and Julia Wienold of HASYLAB station X1 for expert advice on beamline operation.
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